cude STC Silicon tetrachloride
Product Name : Silicon Tetrachloride
Molecular formula : SiCl4
Molecular weight : 169.90
Density (P20, g/cm3 ): 1.483Melting point: -70centigrade Boiling point : 57.6°C Flash point : -9°C
STC specification : Purity 99%↑
CAS No.: 10026-04-7
Appearance : Colorless and transparent
Reuse of by-products[recovery process]By-products in the reduction process for the manufacture of polycrystalline silicon include silicon tetrachloride and hydrogen gas. The silicon tetrachloride is reused as a feedstock for making trichlorosilane in the conversion process, but part of it is refined over and over again to make it ultra-pure, and shipped as a material for making products such as precision optical lenses. The hydrogen gas, the other by-product in the reduction process, is used as a feedstock for the conversion process, and is also reused in the reduction process.
Silicon tetrachloride productionThe process for reducing trichlorosilane with hydrogen produces polycrystalline silicon and also a gas that includes unreacted trichlorosilane, hydrogen chloride, and silicon tetrachloride. This gas is cooled to recover various components individually, and among of them, silicon tetrachloride is highly purified by distillation.
Applications of Silicon tetrachlorideOur ultra-pure silicon tetrachloride can be utilized for uses such as a material for the manufacture of precision optical lenses, a material for the manufacture of synthetic quartz, silicon dioxide, silica and as a photomask for semiconductor manufacture. It is also used for optical fibers.
Silicon tetrachloride
Melting point | −68.74 °C |
Boiling point | 57.65 °C |
Solubility in water | decomposes |
Solubility | soluble in benzene, toluene, chloroform, ether |
Vapor pressure | 25.9 kPa at 20 °C |
Crystal structure | Tetrahedral |
Coordinationgeometry | 4 |
Std enthalpy offormation ΔfHo298 | −687 kJ·mol−1[1] |
Standard molarentropy So298 | 240 J·mol−1·K−1[1] |
MSDS | External MSDS |
EU Index | 014-002-00-4 |
EU classification | Irritant (Xi) |
R-phrases | R14, R36/37/38 |
S-phrases | (S2), S7/8, S26 |
NFPA 704 | |
Other anions | Silicon tetrafluorideSilicon tetrabromideSilicon tetraiodide |
Other cations | Carbon tetrachlorideGermanium tetrachlorideTin(IV) chlorideTitanium tetrachloride |
Related chlorosilanes | ChlorosilaneDichlorosilaneTrichlorosilane |
Structure andproperties | n, εr, etc. |
Thermodynamicdata | Phase behaviourSolid, liquid, gas |
Spectral data | UV, IR, NMR, MS |
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cude STC Silicon tetrachloride